N-H stretch | 3,500–3,100 | - | - | - | - | - | 3,904.4/ 3,457.45 | 3,418.88 | - | - | - | - |
O-H bond; H-bonded | 3,400–3,200 | M | 3,308.21 | 3,289.92 | 3,293.77 | 3,317.05 | 3,304.18 | - | 3,302.68 | 3,293.02 | 3,313.68 | 3,277.43 |
C-H alkanes (stretch) | 3,000–2,850 | S | 2,923.2 | 2,920.62 | 2,919.32 | - | 2,918.6 | 2,923.47 | 2,920.14 | 2,920.77 | 2,929.85 | - |
C-H alkyne (stretch) | 2,900–2,800 | - | 2,858.83 | 2,856.59 | 2,854.95 | - | 2,857.27 | 2,860.04 | 2,856.43 | 2,858.09 | - | - |
C=O aldehyde | 1,740–1,720 | S | 1,740.14 | - | 1,739.31 | - | 1,738.44 | 1,728.54 | - | - | - | - |
C=O ketose | 1,680–1,630 | S | 1,647.99 | 1,646.12 | 1,646.56 | 1,631.67 | 1,647.21 | - | 1,646.68 | 1,646.79 | 1,637.59 | 1,636.07 |
N-H bend | 1,640–1,550 | M-S | - | 1,550.1 | 1,552.21 | - | 1,512.64 | - | 1,546.64 | 1,546.64 | | 1,547.43 |
CH3 bend | 1,450–1,375 | M | 1,447.25 | 1,452.98 | 1,452.67 | 1,435.16 | 1,484.02 | 1,453.96/1,373.53 | 1,450.77 | 1,452.25 | 1,428.75 | 1,422.45 |
C-O alcohols, ethers, COOH | 1,300–1,000 | S | 1,315.01 | 1,240.38 | - | - | - | 1,166.45 | 1,314.57 | - | 1,239.5 | - |
S=O sulfones, sulfonyl chlorides | 1,350–1,140 | S | 1,112.33 | 1,148.74 | - | - | 1,183.68 | - | - | - | 1,103.1 | 1,110.89 |
C-N amines | 1,350–1,000 | M-S | 1,026.11 | - | 1,083.71 | 1,098.97 | 1,026.9 | 1,057.38 | 1,111.28 | 1,090.59 | 1,016.06 | - |
C-H aromatics (out of plane bend) | 900–690 | S | 866.18 | 834.11 | 966.5 | - | 949.19/ 853.71/ 723.09 | 722.82 | - | - | - | - |
C-X chlorine, bromine | 785–540 | S | 555.03/430.13 | 556.98 | - | - | 583.14 | 466.35 | 433.21 | 597.34 | | - |
Functional group present | -CH3-COOHgroup | -COOH-C=O-OH-S=Ogroup | -CH3-COOHgroup | -COOH,-C=O-CH3-N-H-OHgroup | -C=O-N-H-OHgroup | -OH-NH2-S=Ogroup | -COOH,-C=O-CH3-N-H-OHgroup | -C=O-N-H-OHgroup | -COOH-C=O-OH-S=Ogroup | -OH-NH2-S=Ogroup |
Macromolecules present | Lipids | Sugars, amino acids, aglycones | Lipids | Lipids, alkaloids*S=O group present | Alkaloids and aglycone | Proteins | Lipids, alkaloids | Alkaloids and aglycone | Sugars, amino acids, aglycones | Proteins |